Daily charging, monthly compounding
A 22.5% APR is divided by 365 to get the daily rate the card applies to your balance each day. The interest accrues daily, and because it is added straight back to the balance, the next day’s interest is computed on a slightly larger number - that compounding is what makes the total grow a little faster every day it is left alone.
Over a 30-day billing cycle, a $5,000 balance at 22.5% costs roughly $93 of interest. Leave the same balance for a full year and the daily compounding pushes the interest to about $1,258 - more than a flat 22.5% of the original balance, because the interest itself earned interest along the way.